Aspectos hidrogeoquímicos de uma microbacia reflorestada com Eucalyptus grandis no município de Angatuba - São Paulo / Hydrogeochemistry aspects of a Eucalyptus grandis reforested watershed in Angatuba - São Paulo

AUTOR(ES)
DATA DE PUBLICAÇÃO

2009

RESUMO

This study aimed to characterize the Entre Rios stream small watershed hydrogeochemistry, reforested with eucalyptus using materials transport models in dissolved and particulate phases, in periods of sampling, before and after the clearcutting. In the experimental area were collected river water samples, suspended particulate material, rain water, soil and botton sediments. Were determined important parameters and variables such as discharge, major íons concentration, and suspended particulate material, temporal variability and dissolved and particulate transports, punctual and diffuse input mechanisms of the dissolved load, superficial and sub superficial components of the total discharge, concentration and bioavailability of the major heavy metals in soils and bottoms sediments. Hydrochemistry characteristics of the fluvial waters showed that chemical species SiO2, HCO3 -, Ca2+, Mg2+ and Na+ presented dilution behavior with increasing of the discharge and diffuse input, in any period, related to the regional geological formation and watershed recharge mechanisms. Sampling performed five months after the clearcutting showed abnormalities of K+ and Clthat showed increase of their concentrations with the discharge, associated with the agricultural inputs application. The TDS specific transport in the sample before clearcutting was 35.81 kg km-2d-1, and after was 23.53 kg km-2d-1 calculated by the stochastic method. This transport was composed mainly of the SiO2 and HCO3 - and the origin of these species were associated with rock alterations and total atmospheric inputs. In terms of MPS, the concentrations were related positively with the discharge in intensive sampling indicating more haul of this material in the higher discharge with maximum concentrations of the 50.2 and 80.6 mg L-1 before and after clearcutting, respectively. The mechanical erosion showed a soil physical degradation tax of the 8.7 m Ma-1. In relation of atmospherics inputs, the most representative chemical species were Ca2+ and Na+ and HCO3 -, NO3 -, SO4 2-. The TDS specific transport in rain waters was 4.10 t km-2 y-1. The rations between rainwater and river transports demonstrated the control of the atmospheric total contributions in the watershed waters. Cr, Cd, Co, Cu, Zn and Sc were heavy metals with higher concentrations LVd in soil. The soils chemical speciation showed to the LVd soil higher bioavailable fraction for Cd and Zn and were associated mainly with crystalline iron oxides and organic matter, respectively. The enrichment factors results for the 0-10 cm soil layer in the watershed showed no anthropogenic influence caused by cultural treatments, except for the Cu in 0-10 cm LVAd soil layer

ASSUNTO(S)

transport mechanisms hydrochemistry heavy metals metais pesados mecanismos de transporte hidroquímica

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