Desenvolvimento e estudo físico-químico de compósitos de nanotubos de carbono / Physical chemical study and development of carbon nanotubes composites
AUTOR(ES)
Elaine Yoshiko Matsubara
DATA DE PUBLICAÇÃO
2010
RESUMO
This thesis presents for the first time nitrogen-cup-stacked carbon nanotubes with hydrophilic and semiconducting properties synthesized by alcohol precursor. The hybrid carbon fiber/carbon nanotubes composite have three-dimensional geometry and nanostructure. The material was prepared via fixed-bed chemical vapor deposition reactor. In this process nitrogen-cup-stacked, multi-walled or helical carbon nanotubes were synthesized directly onto carbon fibers with different graphitization grade. The composites were analyzed by high resolution scanning and transmission electron microscopy. This characterization showed that the fiber graphitization has influence on the growth. Carbon nanotube density decreases producing a porous composite that was not observed in well-graphitized fibers. The hybrid composite material was studied as a filter, lithium ion battery electrode, electron field emission and as silicone reinforcement. The efficiency to filter several volatile organic compounds present in the mainstream smoke and the development of lithium-ion battery electrodes, aluminum and copper foils free resulted in two patent applications deposit.
ASSUNTO(S)
hydrophilic material material hidrofílico cup-stacked cup-stacked hybrid composite nitrogen-carbon nanotubes nanotubos de carbono nitrogenados compósito híbrido
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