Reaction of tris(bipyridine)ruthenium(III) with hydroxide and its application in a solar energy storage system
AUTOR(ES)
Creutz, Carol
RESUMO
Irradiation of Ru(bipy)32+ (bipy = 2,2′-bipyridine) with light below 560 nm results in the formation of a charge-transfer excited state potentially capable of reducing water to dihydrogen with concomitant production of Ru(bipy)33+. The latter may be reduced by hydroxide [Formula: see text] to form dioxygen and regenerate the starting complex. The use of these reactions in a cell designed to bring about the photochemical decomposition of water is proposed.
ACESSO AO ARTIGO
http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=432876Documentos Relacionados
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