Structure reassignment and absolute configuration of 9-epi-presilphiperfolan-1-ol.

AUTOR(ES)
FONTE

Tetrahedron Letters

DATA DE PUBLICAÇÃO

2011

RESUMO

Reevaluation of 13C NMR data in combination with X-ray diffraction and VCD studies led us to reassign the structure of (−)-epi-presilphiperfolan-1-ol (1), isolated from Anemia tomentosa var. anthriscifolia, to (−)-9-epi-presilphiperfolan-1-ol (2) and to establish its absolute configuration as 1S,4S,7R,8R,9S.

ASSUNTO(S)

anemia tomentosa var. anthriscifolia

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