Synthesis of Dithiocarbamates by Markovnikov Addition Reaction in PEG and Their Application in Amidoalkylation of Naphthols and Indoles

AUTOR(ES)

Halimehjani, Azim Ziyaei, Dadras, Arefeh, Ramezani, Meraj, Shamiri, Elham V., Hooshmand, Seyyed E., Hashemi, Mohammad M.

FONTE

J. Braz. Chem. Soc.

DATA DE PUBLICAÇÃO

2015-07

RESUMO

Synthesis of dithiocarbamates by the one-pot three-component Markovnikov addition reaction of an amine, carbon disulfide and an alkyl vinyl ether or N-vinylpyrrolidone is reported in polyethylene glycol (PEG) under a mild and green procedure with high yields and completely regiospecific. Also, the products were used as efficient starting materials for amidoalkylation of electron-rich arenes such as naphthols and indoles.

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