Brometo De Indio I
Mostrando 1-2 de 2 artigos, teses e dissertações.
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1. Estudo da Aplicação de Brometo de Índio(I) em Reações para Formação de Ligações Carbono-Carbono / Studies on the Application of Indium(I) Bromide in Carbon-Carbon
This PhD thesis describes our results on the application of indium(I) bromide in carbon-carbon bond forming reactions. Indium enolates, generated in situ from the reaction between indium(I) bromide and α,α-dichloroketones, react with carbonyl compounds and electron-deficient alkenes. Reactions of indium enolate with α,α-dichloroketones, i
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 01/03/2011
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2. Assinalação Estereoquímica de Produtos e Descrição de Mecanismos para Reações de Acoplamento entre α,α- Diclorocetonas e Compostos Carbonílicos Promovidas por Brometo de Índio(I) / Indium(I) Bromide-Mediated Coupling of α,α-Dichloroketones with Carbonyl Compounds: Stereochemical Assignments and Description of Reaction Mechanisms
This work describes our results on the use of indium(I) bromide in Organic Synthesis, namely the reaction mechanisms and stereochemical outcome. Indium enolates, generated from the reaction between indium(I) bromide and α,α-dichloroketones, react with carbonyl compounds. The primary coupling with aldehydes leads to the diastereoselective synthesis
Publicado em: 2007