Copolymerization
Mostrando 1-12 de 79 artigos, teses e dissertações.
-
1. Efeito dos ácidos itacônico e fumárico na copolimerização em emulsão do estireno com acrilato de n-butila para produção de argamassa cimentícia
RESUMO Monômeros carboxílicos são frequentemente empregados em formulações de polímeros obtidos via polimerização em emulsão e miniemulsão visando melhorar ás propriedades de aplicação dos látexes. O objetivo deste trabalho foi avaliar o efeito dos ácidos itacônico IAI), fumárico (AF) e metacrílico (AMA) na copolimerização em emulsão do
Matéria (Rio J.). Publicado em: 16/09/2019
-
2. Synthesis and Characterization of Modified Polystyrene with Oleic Acid and an Allyl Ester Derivative
Polystyrene (PS) is one of the most widely used polymers in the world, having a wide applicability. PS can be used in pure or modified forms, and the commercial materials most used for modifications are non-renewable and have high costs. For this reason, studies have been carried in order to evaluate renewable components application such as vegetable oils, f
Mat. Res.. Publicado em: 05/09/2019
-
3. Synthesis of poly(ethyl methacrylate-co-methyl methacrylate) obtained via ATRP using ruthenium benzylidene complexes
Abstract Atom-Transfer Radical Copolymerization (ATRP) of methyl methacrylate (MMA) and ethyl methacrylate (EMA) under different reaction conditions was conducted using Grubbs 1st ( 1) and 2nd (2) generation catalysts. Initially, the study focused on the reactivity of the catalysts in ATRP of EMA individually, then the syntheses of poly(MMA-co-EMA) were als
Polímeros. Publicado em: 10/07/2018
-
4. Chain Elongation Influence in Copolymerization with Different Diesters of Norbornene 2,3-Dicarboxylic Acid Monomers via ROMP under Air Atmosphere
Diesters of norbornene 2,3-dicarboxylic acid (NBE-(COOR)2), in which R is an alkyl group, were synthesized from one-pot synthesis method with 5-norbornene-2,3-dicarboxylic acid and methanol and ethanol. The new monomers were, respectively, the dimethyl ester NBE-(COOCH3)2 and diethyl ester NBE-(COOCH2CH3)2. Norbornene was mixed with these monomers at differe
J. Braz. Chem. Soc.. Publicado em: 2018-06
-
5. A Novel Nanofibrous Film Chemosensor for Highly Selective and Sensitive Optical Signaling of Zn2+
A novel nanofibrous film chemosensor was fabricated by copolymerization and electrospinning, which exhibited signaling behaviors for Zn2+. Upon addition of Zn2+, the sensor film exhibited obvious fluorescence enhancement in a linear fashion. Owing to a larger surface area and high permeability, the selectivity and sensitivity of the nanofibrous film for Zn2+
J. Braz. Chem. Soc.. Publicado em: 2017-10
-
6. Modification of Vietnam Natural Rubber via Graft Copolymerization with Styrene
Graft copolymerization of styrene onto deproteinized natural rubber (DPNR) using tert-butyl hydroperoxide (TBHPO) and tetraethylene pentamine (TEPA) as redox initiator have been investigated. The effects of initiator and monomer concentration on conversion and grafting efficiency were studied. The dynamic mechanical and thermal properties of the graft copoly
J. Braz. Chem. Soc.. Publicado em: 2017-04
-
7. Preparation and characterization of Zn(II) ion-imprinted polymer based on salicylic acrylate for recovery of Zn(II) ions
Abstract This work describes the synthesis of new ion-imprinted polymers (IIPs) for selective solid phase extraction of Zn(II) ions from aqueous samples. IIPs were synthesized by copolymerization of salicylic acrylate (SA) as a functional monomer and ethylene glycol dimethacrylate (EGDMA) as a crosslinker in the presence of 2,2’-azobisisobutyronitrile (AIB
Polímeros. Publicado em: 22/08/2016
-
8. Synthesis and Characterization of Nanopore MoVI-Imprinted Polymer and Its Application as Solid Phase for Extraction, Separation and Preconcentration of Molybdenum Ions from Water Samples
The purpose of this study is to prepare a new ion imprinted polymer for MoVI with high selectivity. Ion-imprinted polymer (IIP) particles were synthesized by thermally copolymerization. For the synthesis of the ion imprinted polymer, the ion pair of (MoVI-thiocyanate) and NR4+ was used. The ion pair was precipitated in an aqueous phase and then dissolved in
J. Braz. Chem. Soc.. Publicado em: 2016-06
-
9. Spectroelectrochemistry of Intrinsically Conducting Selenophene-3-Chlorothiophene Copolymers
The electrochemical copolymerization between selenophene and 3-chlorothiophene monomers was successfully realized. The influence of the applied polymerization potential and the monomer feed ratio on the copolymer properties were investigated, and the results revealed that the obtained polymer films strongly depended on the polymerization conditions. The obta
J. Braz. Chem. Soc.. Publicado em: 2016-05
-
10. Synthesis and characterization of pH and temperature responsive poly(2-hydroxyethyl methacrylate-co-acrylamide) hydrogels
Acrylamide/2-hydroxyethyl methacrylate hydrogels were prepared by simultaneous radiation-induced cross-linking copolymerization of acrylamide (AAm), 2-hydroxyethyl methacrylate (HEMA) and water mixtures at a radiation dose of 10 kGy. Hydrogels were characterized by infrared spectroscopy. Dynamic and equilibrium swelling of hydrogels in water and in buffer so
Polímeros. Publicado em: 04/12/2015
-
11. Synthesis and photostabilizing performance of a polymeric HALS based on 1,2,2,6,6-pentamethylpiperidine and vinyl acetate
Polymeric hindered amine light stabilizers (polymeric HALS) have been extensively studied because they combine a high ability to protect the polymers against harmful effects of weathering with minimum physical loss. In this study a new polymeric N-methylated HALS was synthesized by the radical copolymerization of a cyclic tertiary amine with vinyl acetate (V
Polímeros. Publicado em: 04/12/2015
-
12. Synthesis and Characterization of Poly(Acrylamide-Co-Acrylic Acid) Flocculant Obtained by Electron Beam Irradiation
AbstractThe goal of the paper was to prepare a class of flocculants by free-radical copolymerization of acrylamide with acrylic acid in aqueous solutions in the presence/absence of potassium persulphate as initiator. Reaction medium was submitted to electron beam treatment of 0.6 to 1.5 kGy in atmospheric conditions and at room temperature. Because of the co
Mat. Res.. Publicado em: 2015-10