Electrochemical Method
Mostrando 1-12 de 233 artigos, teses e dissertações.
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1. Additive Manufacturing towards the Fabrication of Greener Electrochemical Sensors for Antioxidants
Additive manufacturing is an emerging tool that has contributed to the sustainable fabrication of devices in several areas based on the concept of “zero waste”. Considering extrusion-based manufacturing (or 3D printing), polylactic acid (PLA) has been highlighted due to its biodegradability, obtention from renewable sources, and compatibility for 3D prin
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. Magnetic and Mesoporous Silica-Niobia Material as Modifier of Carbon Paste Electrode for p-Nitrophenol Electrochemical Determination
In the present work, the sol-gel synthesis method was employed as strategy to obtain a magnetic and mesoporous silica-niobia material. The planned synthesis was based on the hetero-condensation of niobium and silicon alkoxide precursors, in the presence of spherical magnetite particles. The resulting material presented interesting characteristics such as mag
J. Braz. Chem. Soc.. Publicado em: 2021-03
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3. Perovskite-Type Oxides La0.6M0.4Ni0.6Cu0.4O3 (M = Ag, Ba, Ce) towards the Oxygen Reduction Reaction (ORR) in Alkaline Medium: Structural Aspects and Electrocatalytic Activity
In this work, La0.6M0.4Ni0.6Cu0.4O3 (M = Ag, Ba, and Ce, denoted as LANC, LBNC, and LCNC, respectively) electrocatalysts were synthesized by the Pechini method at 1023 K for two hours in air. Rietveld refinement allowed the identification of the crystallographic phases present in all oxides. The electrocatalytic performance of these oxides towards the oxygen
J. Braz. Chem. Soc.. Publicado em: 2021-03
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4. ANODES FOR SOFC: REVIEW OF MATERIAL SELECTION, INTERFACE AND ELECTROCHEMICAL PHENOMENA
This paper presents a comprehensive interface and electrochemical phenomena review of different anodes for SOFC. In this way, it was possible to select some mixed electronic and ionic conductor materials alternatives to the conventional anode, Ni-YSZ conductor. New materials must present a satisfactory electronic and ionic conductivity at intermediate temper
Quím. Nova. Publicado em: 2021-01
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5. QUANTIFICACAO DE NANOPARTICULAS DE PRATA EM UM PRODUTO FARMACEUTICO POR ESPECTROFOTOMETRIA E POTENCIOMETRIA: UMA PROPOSTA PARA AULAS PRATICAS DE QUIMICA ANALITICA
Spectrophotometry and potentiometry techniques were used to quantify silver in an ophthalmic solution. A standard solution of silver nanoparticles was synthesized, from which an analytical method was developed to quantify silver in the sample. Potentiometric titrations of three samples were made, using an electrochemical cell containing an alternative metall
Quím. Nova. Publicado em: 2021-01
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6. Tear down academic paywall during pandemic
Zinc hexacyanoferrate (ZnHCF) is a Prussian Blue analog and can be intercalated by both monovalent and divalent ions. ZnHCF/multi-walled carbon nanotube (MWCNT) film could be used as a cathode for zinc ions battery. Carbon nanotubes improved significantly the electrochemical performance of the electrode. It is described the preparation of ZnHCF/MWCNT films b
Braz. J. Biol.. Publicado em: 2020-09
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7. Electroanalytical Method for Determination of Trace Metals in Struvite Using Electrochemically Treated Screen-Printed Gold Electrodes
We present an electroanalytical method using square-wave anodic stripping voltammetry on electrochemically-treated screen-printed gold electrodes to the simultaneous determination of lead(II), copper(II) and mercury(II) in struvite (natural fertilizer produced from urine). Electrochemical treatment via cyclic voltammetry of the working electrodes increased s
J. Braz. Chem. Soc.. Publicado em: 2020-09
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8. Zinc Hexacyanoferrate/Multi-Walled Carbon Nanotubes Films for Rechargeable Aqueous Batteries
Zinc hexacyanoferrate (ZnHCF) is a Prussian Blue analog and can be intercalated by both monovalent and divalent ions. ZnHCF/multi-walled carbon nanotube (MWCNT) film could be used as a cathode for zinc ions battery. Carbon nanotubes improved significantly the electrochemical performance of the electrode. It is described the preparation of ZnHCF/MWCNT films b
J. Braz. Chem. Soc.. Publicado em: 2020-09
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9. Aqueous Extracts of the Castor Beans as a Corrosion Inhibitor of Mild Steel in HCl Media
The present work studied aqueous extracts of castor beans as a natural inhibitor of the corrosion of mild steel in 1 M HCl using gravimetric tests, potentiodynamic polarization curves, linear polarization method, electrochemical impedance measurements, surface analysis by scanning electron microscopy (SEM) and chemical characterization by Fourier transform i
J. Braz. Chem. Soc.. Publicado em: 2020-06
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10. ELECTROCHEMICAL DETERMINATION OF 2-NAPHTHYLAMINE IN PERFUME SAMPLES USING BORONDOPED DIAMOND ELECTRODE
This work presents a simple electrochemical method for 2-naphthylamine (2NAP) determination in perfume by differential-pulse voltammetry (DPV) employing a boron-doped diamond (BDD) electrode cathodically treated. Simple dilution of sample in supporting electrolyte was performed before electrochemical analysis. A borate buffer solution of pH 10.0 containing 2
Quím. Nova. Publicado em: 2020-03
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11. PMMA-SiO2 Organic-Inorganic Hybrid Coating Application to Ti-6Al-4V Alloy Prepared through the Sol-Gel Method
Siloxane-poly(methyl methacrylate) (PMMA) hybrid was synthesized based on the sol-gel method and applied to Ti-6Al-4V through dip-coating. The structural feature of the hybrid was subjected to Fourier-transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TG); its morphological properties were analyzed through scanning electron microscope (SE
J. Braz. Chem. Soc.. Publicado em: 2020-02
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12. INFLUÊNCIA DA COMPOSIÇÃO DOS NANOFIOS PT-IR/C NA ATIVIDADE CATALÍTICA FRENTE A OXIDAÇÃO ELETROQUÍMICA DE ETANOL EM MEIO ÁCIDO
Carbon-supported platinum-iridium nanowire-shape electrocatalysts containing 20% of metallic loading were synthesized by chemical reduction method using formic acid as a reducing agent and tested towards the oxidation of ethanol in acidic medium. The developed electrocatalysts were synthesized with the following compositions: Pt0.9Ir0.1/C, Pt0.8Ir0.2/C, Pt0.
Quím. Nova. Publicado em: 2020-02