Equilibrio Retro Aldol
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1. Assinalação Estereoquímica de Produtos e Descrição de Mecanismos para Reações de Acoplamento entre α,α- Diclorocetonas e Compostos Carbonílicos Promovidas por Brometo de Índio(I) / Indium(I) Bromide-Mediated Coupling of α,α-Dichloroketones with Carbonyl Compounds: Stereochemical Assignments and Description of Reaction Mechanisms
This work describes our results on the use of indium(I) bromide in Organic Synthesis, namely the reaction mechanisms and stereochemical outcome. Indium enolates, generated from the reaction between indium(I) bromide and α,α-dichloroketones, react with carbonyl compounds. The primary coupling with aldehydes leads to the diastereoselective synthesis
Publicado em: 2007