Hybrid Catalysts
Mostrando 1-12 de 14 artigos, teses e dissertações.
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1. Síntesis y propiedades de electrodos de níquel/grafeno para generación de hidrógeno
ABSTRACT The use of nanomaterials, such graphene oxide (GO), as blocks for the synthesis of hybrid materials has been extensively studied in recent years. In this paper a simple and reproducible method for the synthesis of hybrid nickel/graphene electrodes is presented. This method involves the modification of a conventional electroplating nickel bath by inc
Matéria (Rio J.). Publicado em: 19/07/2018
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2. Ag Nanoparticles-Based Zinc Hydroxide-Layered Hybrids as Novel and Efficient Catalysts for Reduction of 4-Nitrophenol to 4-Aminophenol
Silver nanoparticles and zinc hydroxide-layered hybrid materials (AgNPs/ZHL) have been successfully developed as efficient catalysts for the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) with sodium borohydride. A facile and rapid visible-light assisted green route was used for the deposition of silver nanoparticles (AgNPs) on the external surfac
J. Braz. Chem. Soc.. Publicado em: 2017-01
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3. Oligomerização de olefinas leves catalisada por complexos contendo ligantes B-diimina heterogeneizados em sílica
This work describes ¿-diimine ligands synthesis and the corresponding nickel complexes, homogeneous and heterogeneized, its catalytic application in ethylene oligomerization. Initially held the ¿-diimine ligands synthesis with different substituents in the aromatic ring. These ligands were characterized by CHN elemental analysis, IR, UV-Vis and 1H NRM. Fro
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 2011
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4. Síntese e avaliação de sílica tipo M41S contendo cátions CTA em transesterificação catalítica
The investments in the biofuel production have increased a lot in the last years mainly because of smaller damages they cause to the environment in comparison with the derived conventional petroleum fuels. The reaction of biodiesel formation is denominated transesterification and, nowadays that reaction happens in the presence of homogeneous catalyst as the
Publicado em: 2010
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5. Avaliação do desempenho de catalisadores híbridos Ziegler-Natta/Metaloceno na homo- e copolimerização de etileno / The Performance Evaluation of Hybrid Ziegler-Natta/Metallocene Catalysts in Homo- and Copolymerization of Ethylene
Foram preparados catalisadores híbridos a partir de um catalisador do tipo Ziegler-Natta heterogêneo (MgCl2.TiCl4) e de um metalocênico (CpTiCl3), afim de se obter catalisadores com diferentes tipos de centros ativos. Foi proposta a formação de um novo centro ativo (CpTi(iBu)Cl2) na face 100 do suporte de MgCl2. Estes catalisadores foram avaliados na s�
Publicado em: 2010
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6. Preparação, modoficação, caracterização e aplicação de catalisadores visando a degradação de compostos orgânicos poluentes por processos oxidativos avançados / Preparation, modification, characterization and application of catalysts aiming the degradation of organic pollutant compounds by advanced oxidation processes
Neste trabalho focou-se na preparação de materiais com aplicação em processos de tratamento de compostos orgânicos poluentes. Especificamente, buscou-se correlacionar as propriedades físicas e químicas dos materiais com as suas respostas catalíticas nos processos de fotocatálise heterogênea e de ozonização. Empregando-se o método de precipitaç�
Publicado em: 2010
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7. Effect of polyvinyl alcohol content and after synthesis neutralization on structure, mechanical properties and cytotoxicity of sol-gel derived hybrid foams
Bioactive glass/polymer hybrids are promising materials for biomedical applications because they combine the bioactivity of these glasses with the flexibility of polymers. In this work it was evaluated the effect of increasing the PVA content of the on structural characteristics and mechanical properties of hybrid. The hybrids were prepared with 70 wt. (%) S
Materials Research. Publicado em: 2009-06
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8. SÃntese de esferas hÃbridas e seu desempenho na reaÃÃo de desidrogenaÃÃo do etilbenzeno na presenÃa de diÃxido de carbono / Synthesis of hybrid spheres and their performance in the dehydrogenation reaction of ethylbenzene in carbon dioxide presence
The various possibilities of application of the mesoporous materials, such as catalysis and adsorption, it have encouraged the research in the synthesis of these materials. In addition, but less frequent, synthetic routes have been searched in order to obtain a material whose structure and grain size allow its application in industrial reactors, without the
Publicado em: 2009
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9. DIRECT SYNTHESIS OF HYDROCARBONS FROM SYNTHESIS GAS OVER HYBRID CATALYSTS BASED ON HFERRIERITE ZEOLITE / SÍNTESE DIRETA DE HIDROCARBONETOS A PARTIR DO GÁS DE SÍNTESE SOBRE CATALISADORES HÍBRIDOS BASEADOS EM ZEÓLITA H-FERRIERITA
Existe uma crise energética devido ao excessivo consumo do petróleo e à contaminação em suas diversas formas. Há enormes reservas de gás natural e a conversão deste gás em combustíveis líquidos a partir do gás de síntese, que vem do gás natural, via metanol, e posterior transformação do metanol em hidrocarbonetos é uma interessante alternati
Publicado em: 2008
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10. Metalloporphyrins and salen complexes as a P450 biomimetic model for the metabolism of antiepileptic and antidepressant drugs / Metaloporfirinas e compostos salen como modelos biomiméticos do citocromo P450 no metabolismo de fármacos anticonvulsivante e antidepressivo
In this work, the catalytic activities of metalloporphyrins and the salen complex (Jacobsen catalyst) in solution and immobilized on different supports were studied in the oxidation of hydrocarbons, anticonvulsivant drugs (carbamazepine and primidone) and antidepressives (fluoxetine) by the following oxygen donors: hydrogen peroxide, terc-butyl hydroperoxide
Publicado em: 2008
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11. Análise de desempenho de um motor híbrido utilizando parafina e peróxido e hidrogênio como propelentes / Performance analysis of a hybrid rocket motor using paraffin and hydrogen peroxide as propellants
The objective of this work is to perform a theoretical and experimental analysis of the utilization of paraffin and hydrogen peroxide (H2O2) as propellants in a hybrid propulsion system. Initially, a chemical equilibrium code was written in MATLAB language to determine the propulsive characteristics of those propellants. Next, it was performed an analysis of
Publicado em: 2007
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12. Síntese, caracterização e atividade catalítica de novos catalisadores metaloporfirínicos suportados / Synthesis, characterization and catalytic activity of novel anchored metalloporphyrin catalysts
In this work the second generation metalloporphyrin Me(TFPP)Cl (Me = Fe and Mn) [5,10, 15, 20 ? tetrakis(pentafluorophenyl) porphyrin iron (III) or manganese (III) chloride] was covalently anchored to aminofunctionalyzed supports, through nucleophilic substituition of the para-fluorine atoms of the pentafluorophenyl meso-aryl groups, with the objective of ob
Publicado em: 2004