Ionic Clusters
Mostrando 1-12 de 29 artigos, teses e dissertações.
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1. Solid-state Morphology Evolution of Sodium Neutralized Poly(ethylene-ran-methacrylic acid) Ionomer Under Dry and Wet Thermal Annealing
The DSC low temperature endothermic peak shown by sodium neutralized poly(ethylene-random-methacrylic acid) (E/MAA-Na+) ionomers in the range of 50-70 ºC is attributed to the endothermic reordering of polyethylene chain segments belonging to two populations of quasi-crystals set from melt, initially showing no birefringence. Dry or wet thermal annealing imp
Mat. Res.. Publicado em: 08/08/2019
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2. Estudo da adsorção do líquido iônico [BMIM]+[BF4]sobre γ-Al2O3 por cálculos ab initio
Ionic liquids are, by definition, salts formed by an organic cation and an inorganic anion, with a low melting point. An important application of ionic liquids is that they can replace conventional solvents. Recently, they were also used as cocatalysts (in the form of solvents) for metallic clusters, in the process of removal of aromatics from petroleum. The
Publicado em: 2010
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3. On the solid, liquid and solution structural organization of imidazolium ionic liquids
Sais derivados do cátion 1,3-dialquilimidazólio são uma das mais populares e investigadas classes de líquidos iônicos a temperatura ambiente. Embora, em vários casos, suas propriedades físico-químicas e/ou o resultado dos processos que ocorrem nesses líquidos diferem significantemente daqueles obtidos em solventes orgânicos dipolares, estes ainda p
Publicado em: 2010
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4. Processamento e estudo de ortoniobatos de terras raras e ortotungstatos de metais alcalinos terrosos
Two classes of orthoceramic compounds of general formula ABO4 were investigated in this work. The first group includes the lanthanide orthoniobates (RENbO4, RE = La-Lu, except Pm), which were synthesized by conventional solid-state route at 1150C in different conditions of time aiming the production of crystalline, single phase materials. Alkaline- earth-met
Publicado em: 2010
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5. PROJETO, OTIMIZAÇÃO, SIMULAÇÃO E PREDIÇÃO DE PROPRIEDADES DE NANOESTRUTURAS ATRAVÉS DE TÉCNICAS DA INTELIGÊNCIA COMPUTACIONAL: NANOTECNOLOGIA COMPUTACIONAL INTELIGENTE / DESIGN, OPTIMIZATION, SIMULATION AND PREDICTION OF NANOSTRUCTURES PROPERTIES BY COMPUTATIONAL INTELLIGENCE TECHNIQUES: INTELLIGENT COMPUTATIONAL NANOTECHNOLOGY
This thesis investigates the Intelligent Computational Nanotechnology, that is, the support of Computational Intelligence (CI) techniques in the challenges faced by the Nanoscience and Nanotechnology. For example, Neural Networks are used for build Inference systems able to relate a set of input parameters with the final characteristics of the nanostructures
Publicado em: 2009
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6. Vibrational and thermal characterization of Flemion® membranes / Caracterização vibracional e térmica de membranas flemion®
The behavior of Flemion® membranes on their many applications (among them, fuel cells) is function of series of parameters like how the ionic side groups arrange themselves inside the so called interconnected clustersinside the material. Such arrangement is also function of types and intensities of ionic interactions inside the clusters and how the membrane
Publicado em: 2008
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7. EXPERIMENTAL AND THEORETICAL ANALYSIS OF (NH3)NNHM(+)(-) ION CLUSTERS DESORBED FROM SOLID AMMONIA BOMBARDED BY 65 MEV ION PROJECTILES / ESTUDO TEÓRICO E EXPERIMENTAL DE AGREGADOS IÔNICOS (NH3)NNHM(+)(-) DESSORVIDOS DE AMÔNIA SÓLIDA BOMBARDEADA POR ÍONS DE 65 MEV
Um espectrômetro de massa tipo tempo-de-vôo, montado no Laboratório Nacional de Luz Síncrotron (Campinas - SP), foi utilizado para analisar os íons dessorvidos de uma amostra de amônia condensada (temperaturas de análise: 25 a 150 K) ao ser impactada por fragmentos de fissão do 252Cf. O espectrômetro permite identificar e determinar as abundâncias
Publicado em: 2007
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8. Lithium dynamics in molybdenum disulfide intercalation compounds studied by nuclear magnetic resonance
Cluster architecture and lithium motion dynamics are investigated in nanocomposites formed by the intercalation of lithium and a dialkylamine (diethylamine, dibutylamine and dipentylamine) in molybdenum disulfide by means of 7Li Nuclear Magnetic Resonance (NMR) technique. The present contribution illustrates the potential of the NMR techniques in the study o
Brazilian Journal of Physics. Publicado em: 2006-03
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9. DÉSORPTION IONIQUE INDUITE PAR LASER EN INSULINE, CARBONE ET HALOGÉNURES ALCALINS / DESSORÇÃO INDUZIDA POR LASER EM INSULINA, CARBONO E HALETOS ALCALINOS / LASER INDUCED DESORPTION IN INSULIN, CARBON AND ALKALI HALIDES
O fenômeno de dessorção iônica a partir da incidência de pulsos de radiação laser ultravioleta sobre superfícies em vácuo foi estudada. A dessorção de três tipos diferentes de sólidos foi analisada: insulina, carbono (amorfo e grafite) e policristais de haletos alcalinos. Os processos fundamentais da interação da radiação laser com sólido e
Publicado em: 2006
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10. Síntese e caracterização de alfa-fosfato de zircônio(IV) contendo agregados de cobre metálico
The alpha-zirconium (IV) hydrogenphosphate (alpha-ZrP) has received great attention in the last years due to its properties like ion exchange, intercalation, ionic conductivity and catalytic activity. This work reports a method to produce metallic copper clusters on alpha-ZrP to be used as catalysts in petrochemical processes. It was found that the solids we
Química Nova. Publicado em: 2005-02
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11. Ressonancia paramagnetica do spin eletronico em nitretos de carbono amorfo / Electron spin resonance on amorphous carbon nitrides
Neste projeto de tese de mestrado apresentamos os resultados de medidas de ressonância paramagnética eletrônica (RPE), realizadas em filmes de nitreto de carbono amorfo (a-C1-xNx(:H)), depositados por duas técnicas diferentes, conhecidas como: Glow Discharge (GD) e Dual Ion Beam Assisted Deposition (DIBAD). Os principais parâmetros obtidos como: A conce
Publicado em: 2005
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12. On the formation mechanisms of hydrogen ionic clusters
Structural and thermodynamic properties of hydrogen molecular clusters formed around an atomic or molecular cation are examined. The shell distribution of H2 molecules and the size of the clusters are discussed. The Bloom-Margenau model for predicting the number of neutral molecules that could bind to a cation core is investigated and its limitations are ill
Brazilian Journal of Physics. Publicado em: 2003-12