Lanthanide Complex
Mostrando 1-12 de 24 artigos, teses e dissertações.
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1. Synthesis and anti-myocarditis activity in a multifunctional lanthanide microporous metal-organic framework with 1D helical chain building units
A new microporous lanthanide metal-organic framework, {[Yb(BTB)(H2O) (DEF)2}n (1, DEF=N,N-Diethylformamide), with 1D nano-sized channels has been constructed by bridging helical chain secondary building units with 1,3,5-benzenetrisbenzoic acid (H3BTB) ligand. Structural characterization suggests that this complex crystallizes in the hexagonal space group P61
Braz J Med Biol Res. Publicado em: 11/01/2018
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2. Fases sólidas luminescentes contendo íons lantanídeos : uma proposta para determinação de ácido siálico.
The organofunctionalized silica was used as the solid support in the study of photophysical properties of lanthanides, in particular the Eu (III) ions, which functions as structural probe has been thoroughly discussed seeking new technological applications. In this study, were synthesized two novel organofunctionalized silica matrices and new lanthanide comp
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 27/02/2012
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3. Estudos das propriedades ópticas dos complexos európio tetraciclinas e suas aplicações na detecção de lipoproteínas / Studies of optical properties of complexes europium tetracycline and its applications in detection of lipoproteins
This work presents the optical properties of europium complexes - Tetracyclines (EuTcs) in the presence of LDL and oxidized LDL with potential applications in clinical analysis. Four elements were chosen from the Tetracyclines family: Tetracycline (Tc), Chlortetracycline (CTc), Metatetraciclina (MTc) and Oxytetracycline (OTc) to be part of complexes with eur
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 26/07/2010
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4. SPECTROSCOPIC CHARACTERIZATION OF HYPOCRELLIN B: LANTHANIDE COMPLEXES FOR USE IN PHOTODYNAMIC THERAPY / Caracterização espectroscópica de complexos hipocrelina B: lantanídeos para uso em terapia fotodinâmica
A study about the optical properties of the chromophore hypocrellin B (HB) and of its complexes with lanthanum (La3+), europium (Eu3+) and terbium (Tb3+) ions in ethanol solutions was realized. This pigment is a potential second generation photosensitizer due to its great properties, as high in vivo metabolism and mainly high singlet oxygen generation quantu
Publicado em: 2009
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5. AvaliaÃÃo espectroscÃpica da substituiÃÃo sistemÃtica de molÃculas de Ãgua coordenadas por ligantes β-dicetonas em complexos com Ãons lantanÃdeos
In this work, lanthanide complexes with β-diketones (2,4-pentanedione and trifluoroacetylacetone) and β-keto esters (etil 4,4,4,-trifluoro-2,4- pentanedione) ligands have been synthesized. The complexes showed general formulas: [Ln(acac)(H2O)6]Cl2, [Ln(acac)2(H2O)4]Cl, [Ln(tfa)(H2O)6]Cl2, [Ln(tfa)2(H2O)4]Cl e [Ln(eta)2(H2O)4]Cl. The compounds were
Publicado em: 2008
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6. Desenvolvimento de um biossensor de peróxido de hidrogênio de baixo custo baseado na emissão do európio III. / Development of a low cost hydrogen peroxide biosensor based on europium (III).
In this work was studied the optical properties of Europium-Tetracycline complex (EuTc), determining the best conditions to obtain an efficient complex formation. Optical parameters as absorption, emission, lifetime and refractive index were obtained. Variation of europium complexes concentration, temperature, optimal pH and solutions time reaction were anal
Publicado em: 2008
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7. Estudos conformacionais em compostos contendo íons lantanídeos
Lanthanide macrocyclic complexes, especially containing Gd(III) ions, are largely used as contrast agents in the medical diagnostic technique named Magnetic Resonance Imaging (MRI). Theoretical investigation of these compounds by molecular modeling methods is an emerging research area today. In this work we have performed a conformational study of the follow
Publicado em: 2008
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8. Modelo Sparkle: novos avanÃos para o estudo quÃmico-quÃntico de complexos de lantanÃdeos
Since 1994, the Sparkle Model for Lanthanide Complexes has been used for the calculation of ground state geometries of only Eu(III) complexes. In the present thesis, we evolved the Sparkle Model and advanced Sparkle/AM1 and Sparkle/PM3: new paradigms for semiempirical quantum chemical calculations on lanthanide complexes. Parameterizations for all fifteen tr
Publicado em: 2007
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9. SÃntese e estudo espectroscÃpico de complexos de Ãons lantanÃdeos incorporados em materiais hÃbridos orgÃnicos-inorgÃnicos
In this work two new europium and gadolinium b-diketonate complexes, [Ln(btfa)3(4,4 -bpy)(EtOH)] (Ln = Eu, Gd; 4,4 -bpy = 4,4 -bipyridine; btfa = 4,4,4- trifluoro-l-phenyl- 1,3-butanedione), were prepared and incorporated into a organicinorganic hybrid material. The general formulae of these complexes were confirmed by X-rays single crystal data and elementa
Publicado em: 2007
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10. Sistemas Trinucleares Contendo Ãons LantanÃdeos
Aiming to develop new ligands capable to coordinate most of one lanthanide ions, this work shows the synthesis of trinuclear systems for photonics applications and characterization by elemental analysis, spectroscopic methods (infrared, electronic absorption and NMR of 1H and 13C). A particular study, about the new compounds synthetized, shows the substituti
Publicado em: 2006
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11. Estudo espectroscópico de complexos de Eu3+, Tb3+ E Gd3+ com ligantes derivados de ácidos dicarboxílicos
Complexes of Eu3+, Tb3+ and Gd3+ with dipicolinic acid, chelidamic acid and chelidonic acid have been synthesized in order to study the effect of the substituent groups on the luminescence of the lanthanide complexes. The luminescence of the Eu3+ and Tb3+ complexes was quantified by quantum yield measurements. The complexes of Gd3+ have been used to determin
Química Nova. Publicado em: 2005-10
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12. Novos desenvolvimentos e aplicaÃÃes de mÃtodos de quÃmica quÃntica para compostos de coordenaÃÃo com Ãons lantanÃdeos
Theoretical studies on lanthanide compounds were performed, and divided into three parts: (i) generalization of the Linderberg-Seamans equations for an s-p-d-f basis set; (ii) study of the ligand-to-lanthanide ion charge transfer transitions (LMCT) with the ZINDO98 program using the INDO/S semiempirical hamiltonian and (iii) a study of point charge and charg
Publicado em: 2003