Mercury Electrode
Mostrando 1-12 de 53 artigos, teses e dissertações.
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1. Electrochemical Determination of Trifluralin Herbicide Using Silver Solid Amalgam Electrode: Application in Fresh Food Samples
This paper reports the use of polished silver solid amalgam electrode (p-AgSAE) allied to square wave voltammetry (SWV) in the development of a simple, sensitive, fast and green electroanalytical methodology for the trifluralin herbicide determination in fresh food samples. The experimental (supporting electrolyte and potential and time accumulation) and vol
J. Braz. Chem. Soc.. Publicado em: 2021-07
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2. An Electrochemiluminescence Biosensor for the Determination of Mercury Ion via Dual-Amplification Strategy
A novel dual-signal amplificatory electrochemiluminescence (ECL) deoxyribonucleic acid (DNA) biosensor was designed for the determination of Hg2+. One amplification unit was gold nanoparticles (AuNPs) modified on a glassy carbon electrode, and the other was single-stranded DNA (ssDNA) (with amino at the 3’ terminal and thiol at the 5’ terminal) labeled w
J. Braz. Chem. Soc.. Publicado em: 2020-12
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3. A VERSATILIDADE DO ELETRODO DE GOTA PENDENTE DE MERCÚRIO EM QUÍMICA ANALÍTICA - UMA REVISÃO SOBRE RECENTES APLICAÇÕES
Voltammetry using mercury electrode as working electrode has been employed in the determination of organic and inorganic compounds in several samples. A review on the applications of this analytical tool is present, covering the period of the last ten years. The emphasis of this work is directed to the hanging mercury drop electrode (HMDE), its advantages, d
Quím. Nova. Publicado em: 2018-02
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4. DESEMPENHO DO ELETRODO DE FILME DE PALÁDIO NA DETERMINAÇÃO DE TÁLIO E CHUMBO EM AMOSTRAS DE ÁGUAS NATURAIS POR VOLTAMETRIA DE REDISSOLUÇÃO ANÓDICA COM PULSO DIFERENCIAL
The use of a palladium film electrode (PdFE) as an alternative electrode for the determination of thallium (Tl+) and lead (Pb2+) in water samples by anodic stripping voltammetry is proposed. Preliminary studies of the influence of the substrate were performed on the electrochemical behavior of PdFE prepared ex situ. Using a silver solid amalgam electrode as
Quím. Nova. Publicado em: 2017-09
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5. Low cost UV-Ozone reactor mounted for treatment of electrode anodes used in P-OLEDs devices
Abstract Low cost UV-Ozone reactor using a high pressure mercury vapor lamp of 80 watts without outer bulb showed good results for treatment of ITO films used as anode electrode in the assembly of P-OLED (polymer-organic light emitting diode) devices. This study revealed 20 minutes as effective treatment time and it was verified also that the effect of UV-Oz
Polímeros. Publicado em: 22/08/2016
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6. Degradation of the Dye Reactive Blue 4 by Coupled Photoassisted Electrochemistry at DSA®-Type Electrode
We investigated the photoelectrochemical oxidation of the dye Reactive Blue 4 in the presence of a DSA®-type electrode of nominal composition Ti/Ru0.3Ti0.7O2 under ultraviolet radiation, aiming to enhance the degradation yields of this dye. We conducted the photoelectrocatalytic treatment under galvanostatic control, using an 80 W mercury vapor lamp as the
J. Braz. Chem. Soc.. Publicado em: 2016-05
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7. Sequential Injection Analysis with Square Wave Voltammetry (SI-SWV) Detection for Investigation of Adsorption of Picloram on a Clay Soil
This paper describes a sequential injection analysis method, with detection by square wave voltammetry using a hanging mercury drop electrode, to determine the herbicide picloram in soil extracts (0.010 mol L-1 CaCl2). The method was applied for determination of the Freundlich parameters related to adsorption of picloram on a tropical soil sample. The major
J. Braz. Chem. Soc.. Publicado em: 2015-10
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8. VALIDAÇÃO INTRALABORATORIAL DA DETERMINAÇÃO DE METILTESTOSTERONA EM ÁGUAS NATURAIS POR VOLTAMETRIA USANDO ELETRODO DE GOTA PENDENTE DE MERCÚRIO
17α-methyltestosterone (17α-MT) is a hormone used in medicine and aquaculture which can be found in natural waters. It is considered an emerging organic pollutant and its accurate and precise analysis is required. Therefore, this study presents the in-house validation of a new voltammetric methodology for 17α-MT analysis in natural waters. A hanging mercu
Quím. Nova. Publicado em: 2015-03
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9. Electrochemical reduction and stripping voltammetric determination of the anti-glaucoma drug levobunolol HCl in formulation and human serum at the mercury electrode
Levobunolol HCl é um agente bloqueador ß-adrenoceptor potente e não seletivo usado no tratamento tópico de pressão intraocular aumentada em pacientes com glaucoma de ângulo aberto crônico ou hipertensão ocular. Um método voltamétrico de onda quadrada e redissolução catódico adsortivo (SW-AdCSV) preciso, rápido e sem extração foi descrito para
J. Braz. Chem. Soc.. Publicado em: 2014-08
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10. DESENVOLVIMENTO DE UMA METODOLOGIA ELETROANALÍTICA PARA A DETERMINAÇÃO DE GLIFOSATO EM AMOSTRAS AMBIENTAIS. / DEVELOPMENT OF AN ELECTROANALYTICAL METHODOLOGY FOR DETERMINATION OF GLYPHOSATE IN ENVIRONMENTAL SAMPLES
This paper describes the development of an electroanalytical methodology for the determination of the pesticide glyphosate in environmental samples. The results obtained by square wave voltametry (SWV) in NaNO2 0,10 mol L-1 (pH 6,5) about hanging mercury drop electrode (HMDE) showed that glyphosate has not electroactive response. Thus, the electroactivity of
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 19/04/2012
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11. Voltammetric determination of sibutramine in beverages and in pharmaceutical formulations
A simple and sensitive method has been proposed for the determination of sibutramine-HCl in energy drinks, green tea and pharmaceutical formulations using differential pulse voltammetry performed on a hanging mercury drop electrode. In the chosen experimental condition (Mcllvaine pH 4.0 buffer, 50 mV pulse amplitude and 40 mV s-1 scan velocity), sibutramine-
Química Nova. Publicado em: 2012
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12. PROCEDIMENTO VOLTAMÉTRICO OTIMIZADO PARA DETERMINAÇÃO DE Ni2+ EM AMOSTRAS PRÉ-TRATADAS DE BIODIESEL, USANDO ELETRODO MODIFICADO COM FILME DE MERCÚRIO / PROCEDURE OPTIMIZED VOLTAMMETRIC FOR DETERMINATION OF Ni2 + IN PRE-TREATED SAMPLES OF BIODIESEL, USING MODIFIED ELECTRODE WITH FILM OF MERCURY
A presença de metais no biodiesel pode estar relacionada com a matéria-prima, com o processo utilizado para a obtenção do biodiesel ou com sua estocagem e pode provocar reações de oxidação, corrosão e entupimento em motores, além de causar riscos à saúde humana e ao meio ambiente. Neste trabalho, é proposto um procedimento voltamétrico com base
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 04/07/2011