N Acetylation
Mostrando 1-12 de 217 artigos, teses e dissertações.
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1. Synthesis of Spiro-Pyrrolidinyloxindoles by Oxidative Rearrangement of N-Acyltetrahydro-β-carbolines Using an Oxone/Aqueous Acetone Mixture
Spiro-pyrrolidinyl-2-oxindoles were prepared by the oxidative rearrangement of Na-acetyl-1,2,3,4-tetrahydro-β-carbolines (THBC) using dimethyldioxirane generated in situ. The Na-acetyl THBC substrates were obtained by Pictet-Spengler and acyl-Pictet-Spengler reactions of L-tryptophan methyl ester, followed by Na-acetylation. The stereoselectivity of the oxi
J. Braz. Chem. Soc.. Publicado em: 2019-01
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2. Heterochromatin distribution and histone modification patterns of H4K5 acetylation and H3S10 phosphorylation in Capsicum L.
Abstract We evaluated domesticated Capsicum pepper species from Brazil using classical and molecular cytogenetic techniques, and describe here for the first time their immunostaining patterns using anti-H4K5ac and anti-H3S10ph antibodies. All accessions showed 2n = 24 chromosomes with metacentric and submetacentric morphologies. CMA3 patterns ranged from fou
Crop Breed. Appl. Biotechnol.. Publicado em: 2018-04
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3. Electrospray ionization mass spectrometry applied to study the radical acetylation of amino acids, peptides and proteins
Recentemente nosso grupo demostrou experimentalmente que a hipótese de produção de radical acetil em meio tamponado no sistema diacetil/peroxinitrito era possível. Diacetil é um flavorizante em alimentos, cigarros e bebidas. O peroxinitrito é encontrado na mitocôndria, e em certas condições como um processo de infeção em humanos, a concentração
J. Braz. Chem. Soc.. Publicado em: 2013-12
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4. The epigenetic modifiers 5-aza-2'-deoxycytidine and trichostatin A influence adipocyte differentiation in human mesenchymal stem cells
Epigenetic mechanisms such as DNA methylation and histone modification are important in stem cell differentiation. Methylation is principally associated with transcriptional repression, and histone acetylation is correlated with an active chromatin state. We determined the effects of these epigenetic mechanisms on adipocyte differentiation in mesenchymal ste
Braz J Med Biol Res. Publicado em: 2013-05
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5. Growth rate inhibition of phytopathogenic fungi by characterized chitosans
The inhibitory effects of fifteen chitosans with different degrees of polymerization (DP) and different degrees of acetylation (F A) on the growth rates (GR) of four phytopathogenic fungi (Alternaria alternata, Botrytis cinerea, Penicillium expansum, and Rhizopus stolonifer) were examined using a 96-well microtiter plate and a microplate reader. The minimum
Brazilian Journal of Microbiology. Publicado em: 2012-06
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6. Estudos físico-químicos de N-acetilação de quitosanas em meio homogêneo / Physicochemical studies of N-acetylation chitosan in homogeneous
As principais propriedades físico-químicas da quitosana dependem da massa molar média, grau médio de acetilação (GA) e do parâmetro de acetilação (PA) que expressa o padrão de distribuição das unidades 2-acetamido-2-desoxi-D-glucopiranose (GlcNAc) e 2-amino-2-desoxi-D-glucopiranose ( GlcN) ao longo de sua
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 12/08/2011
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7. Kinetic analysis of batch ethanol acetylation in isothermal non-stationary multiphase systems by lyophilized mycelium of Aspergillus oryzae
A relatively complex network of reactions has been investigated, using as a network model the isothermal batch esterification of acetic acid with ethanol in n-heptane catalyzed by lyophilized mycelium of Aspergillus oryzae. The kinetic analysis was firstly carried out on the whole system, without any simplification, by means of the well-known integral method
Brazilian Journal of Microbiology. Publicado em: 2011-03
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8. Efeito de características estruturais da quitosana sobre sua interação com filmes de Langmuir como modelo de biomembrana / Effects from the structural characteristics of chitosan on its interaction in Langmuir films as biomembrane models.
Chitosans are polysaccharides used in medicine, pharmacy, dentistry and in the inhibition of microorganisms growth (eg. as bactericidal agent). In these applications their action should depend on the interaction with cell membranes, which is difficult to verify because isolating a membrane is not easy. An alternative is to investigate the interaction with me
Publicado em: 2010
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9. Some aspects of acetylation of untreated and mercerized sisal cellulose
Este trabalho apresenta alguns aspectos da acetilação em LiCl/N,N-dimethylacetamida, DMAc de celulose de sisal nativa e mercerizada (sisal e M-sisal). A mercerização da fibra em solução de NaOH resulta nas seguintes alterações: decréscimo de 29.9 % no índice de cristalinidade; diminuição de 16.2% no grau de polimerização e aumento de 9.3% no co
Journal of the Brazilian Chemical Society. Publicado em: 2010
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10. Estudo das acetilações na histona H4 de Trypanosoma cruzi / Study of histone H4 acetylation in Trypanosoma cruzi.
As histonas de Trypanosoma cruzi sao bastante divergentes quando comparadas aos demais eucariotos, principalmente na porcao N-terminal, onde ocorrem modificacoes pos traducionais, que sao reconhecidamente essenciais para o controle da expressao genica e da arquitetura da cromatina. Entre estas modificacoes estao as acetilacoes das lisinas 4, 10 e 14 da histo
Publicado em: 2010
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11. Avaliação de géis obtidos a partir da acetilação da quitosana em meio heterogêneo
Chitosan was acetylated during 2, 5 and 10h and physical gels were obtained at different polymer concentrations in N,N-dimethylacetamide containing 5% of LiCl. Acetylation was confirmed by infrared spectroscopy and 13C NMR, and degrees of acetylation in the range of 0.82-0.91 were determined by NMR. The O-acetylation degree (0.12-0.15) was exclusively determ
Química Nova. Publicado em: 2008
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12. Síntese de organo-seleno aminas e sua resolução cinética via reação de acetilação enantiosseletiva mediada por lipases / Synthesis of organoselenium amines and their kinetic resolution by enantioselective acetylation mediated by lipases
In this work, we have developed a chemoenzymatic method to enantiomerically synthesize enriched organoselenium amines (1-(2, 3 or 4 -(ethylselanyl)phenyl)ethanamine) and amides (N-(1-(2, 3 or 4-(ethylselanyl)phenyl)ethyl)acetamide). Initially, the organoselenium amines, in the racemic form, were synthesized from ortho-, meta- and para- aminoacetophenones. Th
Publicado em: 2008