Radical Polymerization
Mostrando 1-12 de 62 artigos, teses e dissertações.
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1. EFEITO DO PH, ESPÉCIE E CONCENTRAÇÃO IÔNICA NA ABSORÇÃO DE ÁGUA DE HIDROGÉIS BIONANOCOMPÓSITOS CONSTITUÍDOS DE CMC/PAAM/LAPONITA RDS
The objective of this paper was to study the effect of pH, concentration and ionic species on the water absorption of the bionanocomposite hydrogels based on carboxymethylcellulose polysaccharide and laponite nanoclay. Bionanocomposite hydrogels were obtained via free radical polymerization. It was possible to observe that the swelling degree (Q) and kinetic
Quím. Nova. Publicado em: 21/10/2019
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2. Numerical Simulation of Atom-Transfer Radical Polymerization of tert-butyl Methacrylate
Block copolymers based on tert-butyl methacrylate (tBMA) have many uses, such as thermo‐responsive polymers, amphiphilic copolymers, and many applications in the medical field. Atom-transfer radical polymerization (ATRP) is the main technique to produce these controlled macromolecular architectures. This paper provides a simplified kinetic modeling and com
Mat. Res.. Publicado em: 02/09/2019
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3. Thermal radical polymerization of Bis(methacrylamide)s
Abstract Methacrylamides monomers for dental applications were synthesized using a one-step procedure starting from methacrylic anhydride and the respective diamine: N,N’-(propane-1,3-diyl)-bis(N-ethyl-2-methylacrylamide) (1), N,N’-(butane-1,4-diyl)-bis(2-methacrylamide) (2), N,N’-(octane-1,8-diyl-)bis(2-methylacrylamide) (3) and N,N’-(1,4-phenylene)
Polímeros. Publicado em: 27/06/2019
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4. Application of a Novel Ion-Imprinted Polymer to the Separation of Traces of CdII Ions in Natural Water: Optimization by Box-Behnken Design
This study describes the preparation of a novel ion-imprinted polymer (IIP) to apply pre-concentration of cadmium ions in water samples of the Pontal Bay in Ilhéus, Brazil. First, cadmium ion was complexed with 2-(2-thiazolylazo)-p-cresol (TAC). Subsequently, there was the polymerization using ethylene glycol dimethacrylate and methacrylic acid monomers alo
J. Braz. Chem. Soc.. Publicado em: 2019-04
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5. Synthesis and characterization of the photoswitchable poly(methyl methacrylate- random-methacrylate spirooxazine)
Abstract The photoswitchable poly(methyl methacrylate-random-methacrylate spirooxazine) was synthesized via atom transfer radical polymerization with the feed mole ratio of MMA/MSp comonomer of about 5.5/1. Well-defined poly(methyl methacrylate- random-methacrylate spirooxazine) have been obtained with the average molecular weight (Mn) of 6500 g/mol and pol
Polímeros. Publicado em: 18/03/2019
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6. Poly (Methyl Methacrylate)-SiC Nanocomposites Prepared Through in Situ Polymerization
In this study, polymeric nanocomposites based on poly(methyl methacrylate) (PMMA) and silicon carbide (SiC) nanoparticles were prepared by radical mass polymerization in the presence of filler. Nanoparticles of SiC with and without surface treatment with organosilane were obtained .The nanocomposites were characterized by X-ray fluorescence (XRF), infrared s
Mat. Res.. Publicado em: 03/09/2018
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7. Poly(methylene blue)-modified electrode for indirect electrochemical sensing of OH radicals and radical scavengers
ABSTRACT A new modified electrode for indirect sensing of OH· and radical scavengers was described. The electrochemical polymerization of methylene blue in aqueous solutions and the properties of the resulting films on a glassy carbon electrode were carried out using cyclic voltammetry. A surface coverage of 1.11 × 109mol cm2 was obtained, revealing a comp
An. Acad. Bras. Ciênc.. Publicado em: 14/08/2017
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8. Atom Transfer Radical Polymerization of Methyl Methacrylate Mediated by Grubbs 1st and 2nd Generation Catalysts: Insight into the Active Species
Ruthenium benzylidene complexes were evaluated as catalysts in atom-transfer radical polymerization (ATRP) of methyl methacrylate (MMA) under different reaction conditions. The mechanism by which Grubbs 1st and 2nd generation catalysts mediate olefin metathesis has been studied, little is known regarding the mechanism of ATRP reaction promoted by these compl
J. Braz. Chem. Soc.. Publicado em: 2017-08
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9. Development of Molecularly Imprinted Polymers for Solid Phase Extraction of Parabens in Plasma Samples and Analysis by UHPLC-MS/MS
Two molecularly imprinted polymers (MIPs) were synthesized, by sol-gel and radical polymerization procedures. These MIPs were evaluated as selective stationary phases for miniaturized solid phase extraction (MISPE) to determine parabens in plasma samples by ultra-high performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS). Selective cavitie
J. Braz. Chem. Soc.. Publicado em: 2017-02
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10. Efficiency of Single Site Phase Transfer Catalyst in Free Radical Polymerization of Butyl Methacrylate - A Kinetic Study
ABSTRACT The effectiveness of single site phase transfer catalyst- 2- benzoylethyldecyldimethylammonium bromide has been studied with the help of kinetics of free radical polymerization of butyl methacrylate. The radical polymerization was catalysed with single site phase transfer catalyst, initiated by water soluble potassium peroxydisulphate initiator in e
Braz. arch. biol. technol.. Publicado em: 23/01/2017
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11. Simulation of temperature effect on the structure control of polystyrene obtained by atom-transfer radical polymerization
Abstract This paper uses a new kinetic modeling and simulations to analyse the effect of temperature on the polystyrene properties obtained by atom-transfer radical polymerization (ATRP). Differently from what has been traditionaly published in ATRP modeling works, it was considered “break” reactions in the mechanism aiming to reproduce the process at hi
Polímeros. Publicado em: 08/12/2016
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12. Synthesis, Swelling Properties and Evaluation of Genotoxicity of Hydrogels Based on (Meth)acrylates and Itaconic Acid
In this study we prepared hydrogels based on 2-hydroxyethyl methacrylate (HEMA): PHEMA homopolymer and two terpolymers of HEMA, itaconic acid (IA) and two poly(alkylene glycol) (meth) acrylates (PAGM): poly(ethylene glycol)6 acrylate (P(HEMA/IA/PAGM1)) and poly(propylene glycol)5 methacrylate (P(HEMA/IA/PAGM2)). Hydrogels were synthesized by gamma-irradiated
Mat. Res.. Publicado em: 15/08/2016